Raman microscopy in art history and conservation science



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Quimica Nova 21, 1998, pp. 172-5.

80 Vandenabeele, P., Hardy, A., Edwards, H.G.M. and Moens, L., 'Evaluation of a Principal Components-Based Searching Algorithm for Raman Spectroscopic Identification of Organic Pigments in 20th Century Artwork', Applied Spectroscopy 55, 2001, pp. 525-33.

81 Marcolli, C. and Wiedemann, H.G., 'Distinction of Original and Forged Lithographs by Means of Thermogravimetry and Raman Spectroscopy', Journal of Thermal Analysis and Calorimetry 64, 2001, pp. 987-1000.

82 Ciomartan, D.A. and Clark, R.J.H., 'Raman Microscopy Applied to the Analysis of the Pigments Used in Two Persian Manuscripts', Journal of the Brazilian Chemical Society 7, 1996, pp. 395-402.

83 Coupry, C, 'Application of Raman Microspectrometry to Art Objects', Analusis 28, 2000, pp. 39-46.

84 Edwards, H.G.M., Farwell, D.W. and Quye, A., "Dragon's Blood' I - Characterization of an Ancient Resin Using Fourier Transform Raman Spectroscopy', Journal of Raman Spectroscopy 28, 1997, pp. 243-9.

85 Edwards, H.G.M., Farwell, D.W., Perez, F.R. and Villar, S.J., 'Spanish Mediaeval Frescoes at Basconcillos del Tozo: A Fourier Transform Raman Spectroscopic Study', Journal of Raman Spectroscopy 30, 1999, pp. 307-11.

86 Coma, L., Breitman, M. and Ruiz-Moreno, S., 'Soft and Hard Modelling Methods for Deconvolution of Mixtures of Raman Spectra for Pigment Analysis. A Qualitative and Quantitative Approach', Journal of Cultural Heritage 1, 2000, pp. S273-6.

87 Bernard, M.-C, Goff, A.H.-L., Thi, B.V. and Torresi, S.C.de, 'Electrochromic Reactions in Manganese Oxides, I. Raman Analysis', Journal of the Electrochemical Society 140, 1993, pp. 3065-70.

88 Burgio, L., Clark, R.J.H. and Firth, S., 'Raman Spectroscopy as a Means for the Identification of Plattnerite (PbO2), of Lead Pigments and of Their Degradation Products', The Analyst 126, 2001, pp. 222-7.

89 Smith, G.D., Derbyshire, A. and Clark, R.J.H., 'In Situ Spectroscopic Detection of PbS on a Blackened Manuscript Illumination by Raman Microscopy', Studies in Conservation, in press.

90 Smith, G.D., Burgio, L., Firth, S. and Clark, R.J.H., 'Laser-Induced Degradation of Lead Pigments with Reference to Botticelli's Trionfo d'Amore', Analytica Chimica Ada 440, 2001, pp. 185-8.

91 Edwards, H.G.M., Drummond, L. and Russ, J., 'Fourier-Transform Raman Spectroscopic Study of Pigments in Native American Indian Rock Art: Seminole Canyon', Spectrochimica Ada A 54, 1998, pp. 1849-56.

92 Brooke, C.J., Edwards, H.G.M. and Tait, J.K.F., 'The Bottesford Blue Mystery: a Raman Spectroscopic Study of Post-Mediaeval Glazed Tiles', Journal of Raman Spectroscopy 30, 1999, pp.

429-34.

93 Edwards, H.G.M., Drummond, L. and Russ, J., 'Fourier Transform Raman Spectroscopic Study of Prehistoric Rock Paintings from the Big Bend Region, Texas', Journal of Raman Spectroscopy 30, 1999, pp. 421-8.

94 Edwards, H.G.M., Newton, E.M. and Russ, J., 'Raman Spectroscopic Analysis of Pigments and Substrata in Prehistoric Rock Art', Journal of Molecular Structure 550-551, 2000, pp. 245-56.

Vandenabeele, P., von Bohlen, A., Moens, I.., Klockenkamper, R., Joukes, F. and Dewispelaere, G., 'Spectroscopic Examination of Two Egyptian Masks: A Combined Method Approach', Analytical Letters 33, 2000, pp. 3315-32.

Moreno, J., Stodulski, L., Trentelman, K., Jourdan, J. and McCann, L.I., 'An Examination of the Materials and Methods Used in the Creation of Tintoretto's The Dreams of Men', in Goupy, J. and Mohen, J.P., eds, Art et Chimie, la Couleur, CNRS Editions, 2000, pp. 60-3.

Castillejo, M., Martin, M., Silva, D., Stratoudaki, T, Anglos, D., Burgio, L. and Clark, R.J.H., 'Analysis of Pigments in Polychromes by Use of Laser Induced Breakdown Spectroscopy and Raman Microscopy', Journal of Molecular Structure 550-551, 2000, pp. 191-8.

Burgio, L., Melessanaki, K., Doulgeridis, M., Clark, R.J.H. and Anglos, D., 'Pigment Identification in Paintings Employing Laser Induced Breakdown Spectroscopy and Raman Microscopy', Spectrochimica Ada B 56, 2001, pp. 905-13.

Marquardt, B.J., Stratis, D.N., Cremers, D.A. and Angel, S.M., 'Novel Probe for Laser-Induced Breakdown Spectroscopy and Raman Measurements Using an Imaging Optical Fiber', Applied Spectroscopy 52, 1998, pp. 1148-53.

Bruni, S., Cariati, F., Bianchi, C.L., Zanardini, E. and Sorlini, C, 'Spectroscopic Investigation of Red Stains Affecting the Carrara Marble Facade of the Certosa of Pavia', Archaeometry 37, 1995, pp. 249-55.

Toniolo, L., Colombo, S., Bruni, S., Fermo, P., Casoli, A., Palla, G. and Bianchi, C.L., 'Gilded Stuccoes of the Italian Baroque', Studies in Conservation 43, 1998, pp. 201-8.

102 Edwards, H.G.M., Farwell, D.W., Seaward, M.R.D. and Giacobini, C, 'Preliminary Raman Microscopic Analyses of a Lichen Encrustation Involved in the Biodeterioration of Renaissance Frescoes in Central Italy', International Biodeterioration 27, 1991, pp. 1-9.

103 Edwards, H.G.M., Farwell, D.W. and Seaward, M.R.D., 'Raman Spectra of Oxalates in Lichen Encrustations on Renaissance Frescoes', Spectrochimica Ada A 47, 1991, pp. 1531-9.

104 Edwards, H.G.M., Farwell, D.W., Jenkins, R. and Seaward, M.R.D., 'Vibrational Raman Spectroscopic Studies of Calcium Oxalate Monohydrate and Dihydrate in Lichen Encrustations on Renaissance Frescoes', Journal of Raman Spectroscopy 23, 1992, pp. 185-9.

105 Seaward, M.R.D. and F2dwards, H.G.M., 'Biological Origin of Major Chemical Disturbances on Ecclesiastical Architecture Studied by Fourier Transform Raman Spectroscopy', Journal of Raman Spectroscopy 28, 1997, pp. 691-6.

106 Edwards, H.G.M., Gwyer, E.R. and Tait, J.K.F., 'Fourier Transform Raman Analysis of Paint Fragments from Biodeteriorated Renaissance Frescoes', Journal of Raman Spectroscopy 28, 1997, pp. 677-84.

107 Edwards, H.G.M., Farwell, D.W. and Rozenberg, S., 'Raman Spectroscopic Study of Red Pigment and Fresco Fragments from King Herod's Palace at Jericho', Journal of Raman Spectroscopy 30, 1999, pp. 361-6.

108 Sister Daniilia, Sotiropoulou, S., Bikiaris, D., Salpistis, C, Karagiannis, G., Chryssoulakis, Y, Price, B.A. and Carlson, J.H., 'Panselinos' Byzantine Wall Paintings in the Protaton Church, Mount Athos, Greece: A Technical Examination', Journal of Cultural Heritage 1, 2000, pp. 91-110.

109 Edwards, H.G.M., Brooke, C.J. and Tait, J.K.F., 'Fourier Transform Raman Spectroscopic Study of Pigments from English Mediaeval Wall Paintings', Journal of Raman Spectroscopy 28, 1997, pp. 95-8.

110 Perez, F.R., Edwards, H.G.M., Rivas, A. and Drummond, L., 'Fourier Transform Raman Spectroscopic Characterization of Pigments in the Mediaeval Frescoes at Convento de la Peregrina, Sahagun, Leon, Spain. Part 1 - Preliminary Study', Journal of Raman Spectroscopy 30, 1999, pp. 301-5.

111 Edwards, H.G.M., Rull, R, Vandenabeele, P., Newton, E.M., Moens, L., Medina, J. and Garcia, C, 'Mediaeval Pigments in the Monastery of San Baudelio, Spain: A Raman Spectroscopic Analysis', Applied Spectroscopy 55, 2001, pp. 71-6.

112 Edwards, H.G.M., Ellis, E., Farwell, D.W. and Janaway, R.C., 'Preliminary Study of the Application of Fourier Transform Raman Spectroscopy to the Analysis of Degraded Archaeological Linen Textiles', journal of Raman Spectroscopy 27, 1996, pp. 663-9.

113 Edwards, H.G.M. and Falk, M.J., investigation of the Degradation Products of Archaeological Linens by Raman Spectroscopy', Applied Spectroscopy 51, 1997, pp. 1134-8.

114 Coupry, C, Sagon, G. and Gorguet-Ballesteros, P., 'Raman Spectroscopic Investigation of Blue Contemporary Textiles', Journal of Raman Spectroscopy 28, 1997, pp. 85-9.

115 Guineau, B., 'Experiments in the Identification of Colorants In Situ: Possibilities and Limitations', Dyes in History and Archaeology 10, 1992, pp. 55-9.

116 Bourgeois, D. and Church, S.P., 'Studies of Dyestuffs in Fibres by Fourier Transform Raman Spectroscopy', Spectrochimica Ada A 46, 1990, pp. 295-301.

117 Ciomartan, D.A., Clark, R.J.H., McDonald, L.J. and Odlyha, M., 'Studies on the Thermal Decomposition of Basic Lead(II) Carbonate by Fourier-Transform Raman Spectroscopy, X-ray Diffraction and Thermal Analysis', Journal of the Chemical Society, Dalton Transactions 1996, pp. 3639-45.

118 Edwards, H.G.M., Farwell, D.W., Newton, E.M., Perez, F.R. and Villar, S.J., 'Application of FT-Raman Spectroscopy to the Characterisation of Parchment and Vellum, I; Novel Information for Paleographic and Historiated Manuscript Studies', Spectrochimica Ada A 57, 2001, pp. 1223-34.

119 Mannucci, E., Pastorelli, R., Zerbi, G., Bottani, C.E. and Facchini, A., 'Recovery of Ancient Parchment: Characterization by Vibrational Spectroscopy', journal of Raman Spectroscopy 31, 2000, pp. 1089-97.

120 Grosso, V, 'Fourier Transform Infra-red and Raman Spectroscopy of Ancient Paper', in Burgess, H.D., ed., Symposium 88, Conservation of Historic and Artistic Works on Paper, Canadian Conservation Institute, Ottawa, 1988, pp. 245-50.

121 Otieno-Alego, V., Hodgeman, J. and Creagh, D.C., 'Micro-Raman Identification of Bloom Formed on a Historical Print Artifact', journal of the American Institute of Conservation 40, 2001, pp. 35-41.

122 Golovlev, V.V., Gresalfi, M.J., Miller, J.C., Romer, G. and Messier, P., 'Laser Characterization and Cleaning of Nineteenth Century Daguerreotypes', Journal of Cultural Heritage 1, Suppl. 1, 2000, pp. S139-44.

123 Athanassiou, A., Hill, A.E., Fourrier, T., Burgio, L. and Clark, R.J.H., 'The Effects of UV Laser Light Radiation on Artists' Pigments', Journal of Cultural Heritage 1, 2000, pp. S209-13.

124 Gobernado-Mitre, I., Medina, J., Calvo, B., Prieto, A.C., Leal, L.A., Perez, B., Marcos, F. and Frutos, A.M.d., 'Laser Cleaning in Art Restoration', Applied Surface Science 96-8, 1996, pp. 474-8.

125 Kontoyannis, C.G., Orkoula, M.G. and Koutsoukos, P.G., 'Quantitative Analysis of Sulfated Calcium Carbonates Using Raman Spectroscopy and X-ray Powder Diffraction', The Analyst 122, 1997, pp. 33-8.

126 Higuchi, S., Hamada, T. and Gohshi, Y., 'Examination of the Photochemical Curing and Degradation of Oil Paints by Laser Raman Spectroscopy', Applied Spectroscopy 51, 1997, pp. 1218-23.

127 Daniels, V., 'Discoloration of Paper Induced by Pigments Containing Zinc', Restaurator 11, 1990, pp. 236-43.


Authors
Gregory D. Smith, PhD, obtained an undergraduate education at Centre College of Kentucky in chemistry and anthropology and continued his studies in the sciences and archaeology at Duke University, Durham, North Carolina, before earning his doctorate in analytical chemistry in 2000. He is currently a Marshall Sherfield Postdoctoral Fellow at University College London. His research interests include the applications of chemistry in art and archaeology, and he currently serves as an excavation supervisor at two archaeological sites in Israel.

Robin J.H. Clark, D.Sc, FRS, FRSA, FRSC, Hon. FRSNZ, graduated in chemistry at the University of Canterbury, Christchurch, New Zealand, and joined the faculty of University College London in 1962. He has been the Sir William Ramsay professor of chemistry since 1989. His research interests include most aspects of physical inorganic chemistry and spectroscopy, most recently the use of Raman microscopy in the identification and study of pigments on manuscripts and other artefacts.


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